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An "Emergency Response Plan" for pesticide spills is a documented procedure designed specifically to manage and mitigate the effects of pesticide spills. This plan outlines the steps to be taken in the event of a spill to ensure that the situation is dealt with swiftly and safely, minimizing harm to people, the environment, and property.

The plan typically includes instructions on how to contain the spill, protective measures to undertake, notification procedures for authorities or emergency services, and cleanup protocols. By having this plan in place, individuals and organizations can respond effectively to emergencies, ensuring that proper safety measures are followed and that any potential risks are addressed immediately.

The other options, while related to pest management and pesticide use, do not accurately describe the purpose of an emergency response plan. A strategy for purchasing new pesticides focuses on procurement and supply rather than response. A plan to enhance pesticide effectiveness deals with the improvement of product performance and not with spill response. Lastly, a method to report pesticide usage relates to documentation and compliance but does not cover the specifics of managing a spill incident. Therefore, the focus on documented procedures for spill management makes the correct choice clear.